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"Extraction
and Quantification of Hopanes and Steranes in Urban Particulate
Matter Standard Reference Material 1649a"
Kristlyn R.L. Araujo
Mentor: Dr. Randolph K. Larsen III
St. Mary's College of Maryland, 2004- 2005
The following report begins with the topic of Fossil Fuel Biomarkers
and how these compounds can be of help when attempting to determine
the sources and extent of air pollution. Two biomarker classes,
hopanes and steranes, are integral in tracing the presence and source
of one major area of air pollutants: vehicular petroleum combustion.
The Environmental Protection Agency is concerned with keeping PM10
and, more recently, PM2.5 at an acceptable standard according to
human health. However, recent studies show that even smaller particles
called ultrafine particles are equally if not more hazardous to
human health. Fossil fuel biomarkers can be utilized in atmospheric
studies as a correlational tool to trace all three classes of particulate
matter. It is important to determine an exact method of extraction
of these organic compounds from air sample so their concentrations
may be used to their utmost potential. The literature has been explored
for different methods of extraction as well as different methods
of data interpretation so that a singularly effective method for
quantificationa and analysis can be attempted in quantifying hopane
and sterane concentrations in NIST SRM1649a.
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